Synergistic effects of red- and blue-shifting hydrogen bonds in CL-20 host–guest systems: counteracting hyperconjugation to enhance stability

We propose a cooperative mechanism between blue- and red-shifting hydrogen bonds that modulate intramolecular electron redistribution by disrupting hyperconjugation, thereby enhancing the stability of trigger bonds in CL-20 host–guest systems.

Authors

Chongwen Jiang (ORCID: https://orcid.org/0000-0001-6807-9526)
Zhihong Huang (ORCID: https://orcid.org/0000-0003-4569-5400)
Nan Li (ORCID: https://orcid.org/0000-0003-1091-0086)
Xiu-Yuan Li (ORCID: https://orcid.org/0000-0001-5618-4775)
Zihuan Peng

Institutions

Beijing Institute of Technology (CN)

Publication Details

Journal: Journal of Materials Chemistry A
Published: 2025-01-01
DOI: https://doi.org/10.1039/d4ta09136a
Citations: 5
Primary Topic: Analytical Chemistry and Chromatography
Type: article
Field-Weighted Citation Impact: 3.78

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article

Synergistic effects of red- and blue-shifting hydrogen bonds in CL-20 host–guest systems: counteracting hyperconjugation to enhance stability

Chongwen Jiang, Zhihong Huang, Nan Li, Xiu-Yuan Li et al.

Jan 1, 2025

5 citations

Journal of Materials Chemistry A

Analytical Chemistry and Chromatography

3.78

article

Synergistic effects of red- and blue-shifting hydrogen bonds in CL-20 host–guest systems: counteracting hyperconjugation to enhance stability

Chongwen Jiang, Zhihong Huang, Nan Li, Xiu-Yuan Li, Zihuan Peng

January 1, 2025article en

5 citations

Abstract

We propose a cooperative mechanism between blue- and red-shifting hydrogen bonds that modulate intramolecular electron redistribution by disrupting hyperconjugation, thereby enhancing the stability of trigger bonds in CL-20 host–guest systems.

Journal of Materials Chemistry AVol. 13(27)

Beijing Institute of Technology (CN)

Openalex Percentile: Top 7%

Analytical Chemistry and Chromatography

3.78

DOI Source OpenAlex

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