Visible-light-induced radical 1,3-hydrosulfonylation of allylketones with sulfonyl chlorides
A radical 1,3-hydrosulfonylation of allylketones with sulfonyl chlorides <i>via</i> 1,2-carbonyl migration has been achieved under visible-light-irradiation. This reaction proceeds efficiently under mild conditions and exhibits broad substrate scope and excellent functional group tolerance. The synthetic utility of this method is demonstrated by scale-up synthesis and late-stage modification of biologically relevant molecules.
Authors
- Guodong Zhang (ORCID: https://orcid.org/0000-0003-4487-1820)
- Xin Zheng (ORCID: https://orcid.org/0000-0001-5628-7774)
- Xinlong Zhang (ORCID: https://orcid.org/0009-0004-8040-0553)
- Tuanli Yao (ORCID: https://orcid.org/0000-0003-2905-6596)
- Xinglong Han
- Qin Zhang (ORCID: https://orcid.org/0000-0002-4496-0615)
- Xiang Li (ORCID: https://orcid.org/0000-0002-4061-7115)
Institutions
- Shaanxi University of Science and Technology (CN)
- Yangzhou University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc01285f
- Citations
- 4
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 3.74
Funders
- National Natural Science Foundation of China