Pd‐Catalyzed C(sp<sup>2</sup>)−P Cross‐Coupling of Aryl Thianthrenium Salts
The utilization of sulfonium salts in synthesis has gained significant attention in recent years due to their easy-to-handle features and robust reactivity. Herein, we report a Pd/Xantphos-catalyzed C(sp<sup>2</sup>)-P cross-coupling reaction of aryl thianthrenium salts with organophosphorus compounds, including H-phosphonate diesters, H-phosphinate esters, and secondary phosphine oxides. This protocol tolerates an array of functional groups and is applicable to gram-scale synthesis and late-stage functionalization of complex molecules.
Authors
- Li‐Ting Wang (ORCID: https://orcid.org/0000-0002-3335-8055)
- Siyuan Hao (ORCID: https://orcid.org/0000-0001-8247-4207)
- Chao Tian (ORCID: https://orcid.org/0000-0003-0213-2843)
- Lei Shi (ORCID: https://orcid.org/0000-0001-8429-4840)
- Pan Gong (ORCID: https://orcid.org/0009-0007-9929-2224)
Institutions
- Harbin Institute of Technology (CN)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2025-05-29
- DOI
- https://doi.org/10.1002/chem.202501060
- Citations
- 2
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 1.87