Behavior of Uranium, Thorium, and REEs in Oxalate and Oxalate–Formate Media

The behavior of thorium, uranium, and REEs in oxalate and oxalate–formate media was studied. The thorium oxalate solubility in ammonium formate solutions was determined. Recommendations for the uranium separation from thorium and REEs were formulated. It is advisable to precipitate REE oxalates first and then to precipitate thorium oxalate with a nonisotopic carrier.

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Publication Details

Journal
Radiochemistry
Published
2025-04-01
DOI
https://doi.org/10.1134/s1066362225020018
Primary Topic
Radioactive element chemistry and processing
Type
article
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article

Behavior of Uranium, Thorium, and REEs in Oxalate and Oxalate–Formate Media

О. С. Дмитриева, S. S. Poglyad, N. O. Pozigun, V. A. Boldakov et al.
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article

Behavior of Uranium, Thorium, and REEs in Oxalate and Oxalate–Formate Media

О. С. Дмитриева, S. S. Poglyad, N. O. Pozigun, V. A. Boldakov, A. S. Kornilov, E. V. Vasyunina, K. O. Kopaneva, A. R. Zamaltdinova
article en

Abstract

The behavior of thorium, uranium, and REEs in oxalate and oxalate–formate media was studied. The thorium oxalate solubility in ammonium formate solutions was determined. Recommendations for the uranium separation from thorium and REEs were formulated. It is advisable to precipitate REE oxalates first and then to precipitate thorium oxalate with a nonisotopic carrier.

RadiochemistryVol. 67(2)
State Scientific Center - Research Institute of Atomic Reactors (RU)
Openalex Percentile: Top 90%
Radioactive element chemistry and processing
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