An effective and selective non-heme iron-catalyzed hydroxylation of alkane C–H bonds
Mononuclear non-heme iron complexes 1 and 2 demonstrate excellent selectivity in the oxidation of alkanes under ambient conditions. HR-MS combined with EPR analysis identified the involvement of the Fe III -peroxo intermediate.
Authors
- Chen‐Ho Tung (ORCID: https://orcid.org/0000-0001-9999-9755)
- Xiang‐Zhu Wei
- Qi Liu (ORCID: https://orcid.org/0000-0002-6722-2797)
- Li‐Zhu Wu (ORCID: https://orcid.org/0000-0002-5561-9922)
- Xin Xu (ORCID: https://orcid.org/0000-0003-4893-8738)
- Ye Chen (ORCID: https://orcid.org/0000-0002-0664-665X)
- Fang-Jie Liao
Institutions
- Technical Institute of Physics and Chemistry (CN)
- University of Chinese Academy of Sciences (CN)
- University of Hong Kong (HK)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d4qi03130j
- Primary Topic
- Metal-Catalyzed Oxygenation Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.00