Effect of the repeated application of First Contact™ polymer on xenon-difluoride passivated lithium fluoride on aluminum surfaces for space telescopes

The far-UV (FUV) reflectance of the state-of-the-art, broadband UV/optical/IR mirrors of XeF2-passivated LiF on Al (Al + XeLiF) is promising for future space telescope missions. To reach their potential, dependable cleaning procedures and storage methods for such reflective surfaces need to be developed. First Contact™ polymer (FCP) formulations have proven to be a reliable method for cleaning conventional mirror surfaces coated with oxides or bare metal and for protecting them in storage. We report here on studies of the cleaning and storage of Al + XeLiF samples using customized FCP formulations designed by Photonic Cleaning Technologies. Cleaning of such mirrors is demanding since fluoride coatings are softer than oxides and can be moisture sensitive. Any damage that marks the overcoat can lead to catastrophic loss of FUV reflectance due to surface roughening and formation of aluminum oxide, which is FUV opaque. We discovered that one formulation could be successfully applied to and removed from Al + XeLiF coatings multiple times. The coatings retained low roughness, minimal aluminum oxide thickness, and high far-UV reflectance. Another of the four FCP formulations successfully cleaned the Al + XeLiF coatings several times. Variable-angle, spectroscopic ellipsometry, tapping-mode atomic force microscopy, x-ray photoelectron spectroscopy, and FUV reflectance allowed us to observe any changes in reflectance and surface roughness, the formation of aluminum oxide, and damage to coating integrity. From the studies of the range of FCP-fluoride interactions, we noted that too much polymer-to-surface adhesion or exposure to trace water in the polymer can result in coating damage.