A bioinspired electrocatalyst for CO <sub>2</sub> electroreduction to ethanol <i>via</i> secondary-sphere synergy in Fe porphyrinic-based metal–organic frameworks
An enzyme-inspired Fe–porphyrin MOF catalyst with secondary-sphere functionalities enables efficient and selective CO 2 electroreduction to ethanol via tilted *CO adsorption and proton-shuttled hydrogenation through hydrogen-bonding networks.
Authors
- Kaian Sun
- Shuyu Xie (ORCID: https://orcid.org/0009-0002-8779-0174)
- Ping Guan
- Xin Tan (ORCID: https://orcid.org/0000-0001-7710-7103)
- Zewen Zhuang (ORCID: https://orcid.org/0000-0002-7060-426X)
- Chen Chen (ORCID: https://orcid.org/0000-0001-5902-3037)
- Wei Yan (ORCID: https://orcid.org/0000-0002-2598-075X)
- Jiujun Zhang (ORCID: https://orcid.org/0000-0002-6858-4060)
Institutions
- Fuzhou University (CN)
- Tsinghua University (CN)
Publication Details
- Journal
- Energy & Environmental Science
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ee01388g
- Citations
- 6
- Primary Topic
- CO2 Reduction Techniques and Catalysts
- Type
- article
- Field-Weighted Citation Impact
- 2.18