Hydrogeochemical and Isotopic Approach to Groundwater Management in a Mediterranean City Dependent on External Water Supply (Aix-en-Provence, SE France)

Drought frequency and severity intensify with climate change, challenging many Mediterranean cities to face securing sustainable water supplies. In this context, groundwater emerges as a key but often overlooked resource, particularly in urban areas historically reliant on external drinking water systems. This study provides a comprehensive hydrogeological characterisation of the groundwater system in Aix-en-Provence (southeastern France), with a specific focus on hypothermal springs and the cold springs of the Vallon des Pinchinats, which historically supplied the town before the creation of the Canal de Provence by the company of the same name (Société du Canal de Provence (SCP)). By combining chemical and isotopic analyses (δ18O, δ2H, and chloride concentrations) with a statistical clustering (DACMAD method), we characterise the origin and dynamics of distinct water sources and evaluate their influence with surface water and external supply systems. Four key hydrological entities influencing the study area were identified. (1) regional precipitation (RRW) contributing significantly to groundwater recharge in the region. The isotope composition of the RRW was calculated (δ18O: −6.68‰, δ2H: −41.80‰, Cl: 2.2 mg/L) (2) Groundwater from the Oligocene aquifer (OG) characterised by an enrichment in chloride and sulphate. (3) Groundwater from the Cretaceous–Jurassic aquifer (CJG), a karstified aquifer from the Sainte-Victoire-Concors massif, which supplies the cold and hypothermal springs in Aix-en-Provence and multiple springs in the region. (4) Canal de Provence water (CPW) as an external water source, used for domestic supply, which has left a traceable signal in the local hydrosystem. The study reveals that cold springs of the Vallon des Pinchinats result from the mixing of Oligocene and Cretaceous–Jurassic groundwaters. Hypothermal springs (20–30 °C) circulate at moderate depths (165–500 m), unlike previous models suggesting deeper infiltration and mixing processes. This study contributes a novel hydrogeochemical and isotopic framework applicable to other Mediterranean urban areas facing similar pressures and highlights the strategic role that local groundwater can play in building long-term water resilience.