An intelligent ion-sieving bridge enabled by a zinc-rich artificial SEI layer with high Zn<sup>2+</sup>-conductivity for reversible zinc metal anodes
A zinc-rich artificial solid-electrolyte interphase (SEI) layer with high Zn<sup>2+</sup>-conductivity composed of zinc titanate (ZTO), serving as an intelligent ion-sieving bridge, facilitates rapid migration of Zn<sup>2+</sup> rather than anions to the Zn surface, realizing uniform Zn deposition and inhibition of side reactions. Consequently, the ZTO@Zn anodes exhibit a long-term reversible Zn plating/stripping (4500 h) and a high coulombic efficiency (99.9%).
Authors
- Huaisheng Ao (ORCID: https://orcid.org/0000-0003-1964-831X)
- Jian Rong (ORCID: https://orcid.org/0000-0002-0307-2363)
- Yixin Fang (ORCID: https://orcid.org/0000-0001-9129-5358)
- Xiaofeng Bao (ORCID: https://orcid.org/0000-0002-9210-5322)
- Rong Wang (ORCID: https://orcid.org/0000-0001-8257-0282)
- Ruisi Zhang
- Yuzhe Zhang (ORCID: https://orcid.org/0000-0002-3975-4665)
- Zhongyu Li (ORCID: https://orcid.org/0000-0001-6314-1298)
- Tao Ma (ORCID: https://orcid.org/0000-0001-5448-4387)
- Xuekun Zhu
Institutions
- Changzhou University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02227d
- Primary Topic
- Advanced battery technologies research
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Changzhou University