Visible-light mediated oxidative Diels-Alder reaction of hydroxylamines and 1,3-dienes
Visible-light-photoredox-catalyzed oxidative Diels-Alder reaction of hydroxylamines and 1,3-dienes was developed, accessing to various 3,6-dihydro-1,2-oxazines in good to excellent isolated yields. Distinct advantages, including mild reaction conditions, air as the terminal oxidant , as well as exceptional substrate tolerance with the present protocol. A visible-light photoredox catalyzed oxidative Diels-Alder reaction of hydroxylamines and 1,3-dienes was disclosed using the air as terminal oxidant, accessing to 3,6-dihydro-1,2-oxazines in good yields.
Authors
- Lanqin Liu (ORCID: https://orcid.org/0000-0001-8379-6240)
- Meijun Zhu
- Hong Hou (ORCID: https://orcid.org/0000-0002-9103-9888)
- Yunfei Zhi
Institutions
- Yangzhou Polytechnic Institute (CN)
- Yangzhou University (CN)
Publication Details
- Journal
- Tetrahedron
- Published
- 2025-05-27
- DOI
- https://doi.org/10.1016/j.tet.2025.134752
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Natural Science Foundation of Jiangsu Province
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions