Group IIIA Metal-Capped {M<sub>2</sub>(H<sub>2</sub>O)[P<sub>4</sub>Mo<sub>6</sub>O<sub>31</sub>]<sub>2</sub>}-Based Phosphomolybdates (M = Al<sup>3+</sup>, Ga<sup>3+</sup>)
Group IIIA metal Al<sup>3+</sup>/Ga<sup>3+</sup>-capped {M<sub>2</sub>(H<sub>2</sub>O)[P<sub>4</sub>Mo<sub>6</sub>O<sub>31</sub>]<sub>2</sub>}-based phosphomolybdates were synthesized by adjusting the reducing agents, in which two [P<sub>4</sub>Mo<sup>VI</sup><sub>4</sub>Mo<sup>V</sup><sub>2</sub>O<sub>31</sub>]<sup>8-</sup> half-units are joined in a face-to-face mode and are capped by two M<sup>3+</sup>/[M(H<sub>2</sub>O)]<sup>3+</sup> cations on both sides. This type of {M<sub>2</sub>(H<sub>2</sub>O)[P<sub>4</sub>Mo<sub>6</sub>O<sub>31</sub>]<sub>2</sub>} hybrids showed excellent photocatalytic activities in the Cr(VI) reduction reaction.
Authors
- Hao‐Xue Bi
- Zhengguo Lin (ORCID: https://orcid.org/0000-0002-9628-6888)
- Zhangang Han (ORCID: https://orcid.org/0000-0002-9758-6735)
- Jing Du (ORCID: https://orcid.org/0000-0001-6609-3164)
- Yuan‐Yuan Ma (ORCID: https://orcid.org/0000-0002-7379-4257)
- Ziyi Zhang (ORCID: https://orcid.org/0000-0001-9102-8292)
- Yaqi Zhang (ORCID: https://orcid.org/0000-0002-5158-2683)
- Yuqing Liu (ORCID: https://orcid.org/0000-0002-6324-1296)
Institutions
- Hebei Normal University (CN)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2025-05-26
- DOI
- https://doi.org/10.1021/acs.inorgchem.5c01379
- Citations
- 4
- Primary Topic
- Polyoxometalates: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 2.07
Funders
- National Natural Science Foundation of China
- China Postdoctoral Science Foundation
- Hebei Normal University
- Department of Education of Hebei Province
- Natural Science Foundation of Hebei Province
- Hebei Provincial Department of Bureau of Science and Technology