Cyclometallated phosphonium ylide-based iridium(<scp>iii</scp>) photocatalysts
A novel class of cyclometallated photoactive iridium(III) complexes containing phosphonium ylide ligands has been synthesized and thoroughly characterized. Their photophysical and redox properties have been systematically investigated and employed in photocatalytic applications. Notably, these complexes exhibit high activity in visible-light-mediated EnT and SET processes.
Authors
- Olivier Baslé (ORCID: https://orcid.org/0000-0002-4551-473X)
- Yves Canac (ORCID: https://orcid.org/0000-0002-3747-554X)
- Jean‐Baptiste Sortais (ORCID: https://orcid.org/0000-0003-1178-8588)
- Carine Duhayon (ORCID: https://orcid.org/0000-0001-7345-8782)
- Oussama Fayafrou (ORCID: https://orcid.org/0009-0000-0047-0174)
- Juliette Zanzi
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université Toulouse III - Paul Sabatier (FR)
- Université Fédérale de Toulouse Midi-Pyrénées (FR)
- Laboratoire de Chimie de Coordination (FR)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02320c
- Citations
- 2
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 1.87
Funders
- Centre National de la Recherche Scientifique