Understanding alkali-metal driven hydrophosphorylation: mechanism and challenges in the Pudovik reaction
DFT studies clarify the roles of alkali metal cations and P-substituents in the H–P addition and formation and possible deactivation reactions of the catalytically active phosphinites in alkyne hydrophosphorylation promoted by M-HMDS precatalysts.
Authors
- Gregori Ujaque (ORCID: https://orcid.org/0000-0001-5896-9998)
- Matthias Westerhausen (ORCID: https://orcid.org/0000-0002-1520-2401)
- Agustı́ Lledós (ORCID: https://orcid.org/0000-0001-7909-422X)
- Irina Bozhinovska
Institutions
- Universitat Autònoma de Barcelona (ES)
- Friedrich Schiller University Jena (DE)
Publication Details
- Journal
- Catalysis Science & Technology
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cy00269a
- Citations
- 2
- Primary Topic
- Organophosphorus compounds synthesis
- Type
- article
- Field-Weighted Citation Impact
- 1.87
Funders
- Ministerio de Ciencia, Innovación y Universidades
- European Commission
- California State University, Chico
- Agencia Estatal de Investigación