Reclamation of available phosphorus and separation of heavy metals from sewage sludge via FeCl3-assisted electrokinetic treatment and pyrolysis

Recycling of sewage sludge and the endogenous phosphorus (P) is a promising strategy for sustainable development, while the disposal of heavy metals (HMs) in sewage sludge and the recovery of targeted P species remain challenges. An innovative method coupling electrokinetic treatment with pyrolysis was proposed in the present study to achieve the effective reclamation of available P and the separation of HMs from sewage sludge. The pristine and FeCl₃-assisted electrokinetic treatment were employed for the removal of HMs from sewage sludge and to modify the P species, and the subsequent pyrolysis (300-700 °C) was conducted for the recovery of available P along with the production of biochar. The X-ray absorption near-edge spectroscopy (XANES), ³¹P liquid nuclear magnetic resonance (NMR) spectroscopy, and sequential chemical extraction were used to systematically determine the evolution of P during the combined treatment of sewage sludge. 19.69-24.80 % of Ni, Cu, and Zn were removed from sewage sludge after pristine electrokinetic treatment, and the HM removal efficiency was further elevated to 47.01-56.86 % with the assistance of FeCl₃. Consequently, in comparison with the raw sewage sludge-derived biochars (SBs), the biochars derived from FeCl₃-assisted electrokinetic treated sewage sludge (FESBs) contained much lower HM contents and showed higher stability of HMs. The FeCl₃-assisted electrokinetic treatment converted alkaline biochars dominated by poorly soluble Ca-phosphates into neutral to slightly acidic biochars dominated by Al/Fe-associated phosphates. This transformation greatly improved the available P concentrations determined by diffusive gradients in thin film in FESBs by 0.6-1.3 folds compared to untreated SBs. Therefore, coupling FeCl₃-assisted electrokinetic treatment with pyrolysis could be a promising strategy to achieve the reclamation of available P and the separation of HMs from sewage sludge.