CCl<sub>4</sub>-Induced Synthesis of Phosphonothioates, Sulfoxides, and Sulfones from Sodium Sulfinates
An external reductant-free and acid-free synthesis of phosphonothioates from odorless sodium sulfinates induced by CCl<sub>4</sub> (1.0 equiv) under mild conditions has been achieved. This transformation provides an efficient synthetic approach to phosphonothioates in up to 98% yield with good functional group compatibility. In addition, an unexpected CCl<sub>4</sub>-induced synthesis of sulfoxides and sulfones from sodium sulfinates using DMSO as the solvent has been developed.
Authors
- Yanping Huo (ORCID: https://orcid.org/0000-0003-4124-6026)
- Yang Gao (ORCID: https://orcid.org/0000-0001-9513-6899)
- Nan Huang (ORCID: https://orcid.org/0000-0002-5246-6369)
- Silong Chen
- Qian Chen (ORCID: https://orcid.org/0000-0002-0818-6028)
- Xianwei Li (ORCID: https://orcid.org/0000-0002-4014-6712)
- Xiangyun Yang
Institutions
- Guangdong University of Technology (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2025-05-23
- DOI
- https://doi.org/10.1021/acs.joc.5c00586
- Citations
- 3
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 2.81