A Systematic Study of Electrolyte Sulfonate Additives for All-Vanadium Flow Batteries

A sulfonate additive featuring an optimal ligand significantly enhances the high-and low-temperature stability of the electrolyte. Through the synergistic effect of morpholine and sulfonic groups, the utilization rate of vanadium ions is remarkably increased by 23.3% after 100 cycles. This finding offers crucial insights for the development of low-cost and widely applicable vanadium-based flow batteries.

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Publication Details

Journal
ACS Applied Energy Materials
Published
2025-05-22
DOI
https://doi.org/10.1021/acsaem.5c00592
Primary Topic
Advanced battery technologies research
Type
article
Field-Weighted Citation Impact
0.00

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article

A Systematic Study of Electrolyte Sulfonate Additives for All-Vanadium Flow Batteries

Lishan Yang, Hang Sheng, Kangning Liu, Xiongwei Wu et al.
ACS Applied Energy Materials
Advanced battery technologies research
article

A Systematic Study of Electrolyte Sulfonate Additives for All-Vanadium Flow Batteries

Lishan Yang, Hang Sheng, Kangning Liu, Xiongwei Wu, Wei Ling, Sheng‐Jia Dai, Xi Chen, Hongyi Liu, Zhuo Liu, Zheng-He Xie
article en

Abstract

A sulfonate additive featuring an optimal ligand significantly enhances the high-and low-temperature stability of the electrolyte. Through the synergistic effect of morpholine and sulfonic groups, the utilization rate of vanadium ions is remarkably increased by 23.3% after 100 cycles. This finding offers crucial insights for the development of low-cost and widely applicable vanadium-based flow batteries.

ACS Applied Energy MaterialsVol. 8(11)
Hunan Normal University (CN), Chinese Academy of Sciences (CN), Energy Foundation (CN), Energy International (United States) (US), China Minmetals (China) (CN), Shaanxi Yulin Energy Group (CN), Hunan Agricultural University (CN)
Education Department of Hunan Province, Hunan Provincial Science and Technology Department, Natural Science Foundation of Hunan Province, National Key Research and Development Program of China
Clean water and sanitation
Openalex Percentile: Top 91%
Advanced battery technologies research
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