Emergent scales and spatial correlations at the yielding transition of glassy materials
Glassy materials yield under large external mechanical solicitations. Under oscillatory shear, yielding shows a well-known rheological fingerprint, common to samples with widely different microstructures. At the microscale, this corresponds to a transition between slow, solidlike dynamics and faster liquidlike dynamics, which can coexist at yielding in a finite range of strain amplitudes. Here we capture this phenomenology in a lattice model with two main parameters: glassiness and disorder, describing the average coupling between adjacent lattice sites, and their variance, respectively. In absence of disorder, our model yields a law of correspondent states equivalent to trajectories on a cusp catastrophe manifold, a well-known class of problems including equilibrium liquid-vapor phase transitions. Introducing a finite disorder in our model entails a qualitative change, to a continuous and rounded transition, whose extent is controlled by the magnitude of the disorder. We show that a spatial correlation length $\ensuremath{\xi}$ emerges spontaneously from the coupling between disorder and bifurcating dynamics. With vanishing disorder, $\ensuremath{\xi}$ diverges and yielding becomes discontinuous, suggesting that the abruptness of yielding can be rationalized in terms of a length scale of dynamic heterogeneities.
Authors
- Stefano Aime (ORCID: https://orcid.org/0000-0002-0357-6983)
- Domenico Truzzolillo (ORCID: https://orcid.org/0000-0002-1841-969X)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université de Montpellier (FR)
- Chimie Moléculaire, Macromoléculaire, Matériaux (FR)
- Laboratoire Charles Coulomb (FR)
- ESPCI Paris (FR)
Publication Details
- Journal
- Physical Review Materials
- Published
- 2025-05-22
- DOI
- https://doi.org/10.1103/physrevmaterials.9.055602
- Primary Topic
- Material Dynamics and Properties
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Agence Nationale de la Recherche
- Centre National d’Etudes Spatiales