Emergent scales and spatial correlations at the yielding transition of glassy materials

Glassy materials yield under large external mechanical solicitations. Under oscillatory shear, yielding shows a well-known rheological fingerprint, common to samples with widely different microstructures. At the microscale, this corresponds to a transition between slow, solidlike dynamics and faster liquidlike dynamics, which can coexist at yielding in a finite range of strain amplitudes. Here we capture this phenomenology in a lattice model with two main parameters: glassiness and disorder, describing the average coupling between adjacent lattice sites, and their variance, respectively. In absence of disorder, our model yields a law of correspondent states equivalent to trajectories on a cusp catastrophe manifold, a well-known class of problems including equilibrium liquid-vapor phase transitions. Introducing a finite disorder in our model entails a qualitative change, to a continuous and rounded transition, whose extent is controlled by the magnitude of the disorder. We show that a spatial correlation length $\ensuremath{\xi}$ emerges spontaneously from the coupling between disorder and bifurcating dynamics. With vanishing disorder, $\ensuremath{\xi}$ diverges and yielding becomes discontinuous, suggesting that the abruptness of yielding can be rationalized in terms of a length scale of dynamic heterogeneities.

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Publication Details

Journal
Physical Review Materials
Published
2025-05-22
DOI
https://doi.org/10.1103/physrevmaterials.9.055602
Primary Topic
Material Dynamics and Properties
Type
article
Field-Weighted Citation Impact
0.00

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article

Emergent scales and spatial correlations at the yielding transition of glassy materials

Stefano Aime, Domenico Truzzolillo
4 links
Physical Review Materials
Material Dynamics and Properties
article

Emergent scales and spatial correlations at the yielding transition of glassy materials

Stefano Aime, Domenico Truzzolillo
article en

Abstract

Glassy materials yield under large external mechanical solicitations. Under oscillatory shear, yielding shows a well-known rheological fingerprint, common to samples with widely different microstructures. At the microscale, this corresponds to a transition between slow, solidlike dynamics and faster liquidlike dynamics, which can coexist at yielding in a finite range of strain amplitudes. Here we capture this phenomenology in a lattice model with two main parameters: glassiness and disorder, describing the average coupling between adjacent lattice sites, and their variance, respectively. In absence of disorder, our model yields a law of correspondent states equivalent to trajectories on a cusp catastrophe manifold, a well-known class of problems including equilibrium liquid-vapor phase transitions. Introducing a finite disorder in our model entails a qualitative change, to a continuous and rounded transition, whose extent is controlled by the magnitude of the disorder. We show that a spatial correlation length $\ensuremath{\xi}$ emerges spontaneously from the coupling between disorder and bifurcating dynamics. With vanishing disorder, $\ensuremath{\xi}$ diverges and yielding becomes discontinuous, suggesting that the abruptness of yielding can be rationalized in terms of a length scale of dynamic heterogeneities.

Physical Review MaterialsVol. 9(5)
Centre National de la Recherche Scientifique (FR), Université de Montpellier (FR), Chimie Moléculaire, Macromoléculaire, Matériaux (FR), Laboratoire Charles Coulomb (FR), ESPCI Paris (FR)
Agence Nationale de la Recherche, Centre National d’Etudes Spatiales
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Material Dynamics and Properties
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