Equilibrium phases and phase transitions in multicritical magnetic polymers

Magnetic polymers are examples of composite soft materials in which the competition between the large configurational entropy of the soft substrate (polymer) and the magnetic interaction may give rise to rich equilibrium phase diagrams as well as non-standard critical phenomena. Here, we study a self-avoiding walk model decorated by Ising spins of value 0 and ±1 that interact according to a Blume-Emery-Griffith-like Hamiltonian. By using mean-field approximations and Monte Carlo simulations, we report the existence of three distinct equilibrium phases: swollen disordered, compact ordered, and compact disordered. Notably, these phases are separated by phase boundaries that meet at multicritical points, whose nature and location are tunable and depend on the strength of the interactions. In our conclusion, we discuss the relevance of the phase diagrams we have obtained to the physics of magnetic polymers and their application to chromatin biophysics.

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Publication Details

Journal
Soft Matter
Published
2025-01-01
DOI
https://doi.org/10.1039/d5sm00212e
Primary Topic
Protein Structure and Dynamics
Type
article
Field-Weighted Citation Impact
0.00

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article

Equilibrium phases and phase transitions in multicritical magnetic polymers

Davide Marenduzzo, Emanuele Locatelli, Enzo Orlandini, Alberto Raiola
Soft Matter
Protein Structure and Dynamics
article

Equilibrium phases and phase transitions in multicritical magnetic polymers

Davide Marenduzzo, Emanuele Locatelli, Enzo Orlandini, Alberto Raiola
article en

Abstract

Magnetic polymers are examples of composite soft materials in which the competition between the large configurational entropy of the soft substrate (polymer) and the magnetic interaction may give rise to rich equilibrium phase diagrams as well as non-standard critical phenomena. Here, we study a self-avoiding walk model decorated by Ising spins of value 0 and ±1 that interact according to a Blume-Emery-Griffith-like Hamiltonian. By using mean-field approximations and Monte Carlo simulations, we report the existence of three distinct equilibrium phases: swollen disordered, compact ordered, and compact disordered. Notably, these phases are separated by phase boundaries that meet at multicritical points, whose nature and location are tunable and depend on the strength of the interactions. In our conclusion, we discuss the relevance of the phase diagrams we have obtained to the physics of magnetic polymers and their application to chromatin biophysics.

Soft MatterVol. 21(26)
University of Padua (IT), Istituto Nazionale di Fisica Nucleare, Sezione di Padova (IT), University of Edinburgh (GB)
Ministero dell’Istruzione, dell’Università e della Ricerca
Openalex Percentile: Top 90%
Protein Structure and Dynamics
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