MOF-derived N-doped porous carbon nanorods supporting NiCo@Pt for enhanced electrocatalytic methanol oxidation

Several innovative Platinum-based catalysts employing diverse metal-organic frameworks (MOF)-derived materials to alloy Pt with transition metals (Ni, Co) and integrating them into nitrogen-doped porous carbon (NPC) nanorod frameworks, NiCo@Pt/NPC, were prepared, which have unique properties for electrocatalytic methanol oxidation reaction (MOR). The structure properties of NiCo@Pt with NPC supporting layer were explored by several characterizations such as XPS, FTIR, EDS, and XRD. Moreover, the structure-activity relationship of NiCo@Pt/NPC was carefully studied. The NiCo@Pt/NPC-T₈₀₀-X₁₅-t₁₅ exhibited exceptional performance of methanol oxidation, with a mass activity reaching 821.4 mA·mg_Pt^-1, 2.4 times higher than that of commercial Pt/C. Furthermore, compared with the commercial Pt/C, it maintained a steady-current density 7.7 times higher. Compared with commercial Pt/C, the CO intermediate peak potential exhibited a 57-mV negative shift, primarily attributed to the interfacial effects between NiCo@Pt nanoparticles and NPC of the composite material, improving electron transport and preventing nanoparticle agglomeration, thereby considerably increasing MOR efficiency. This study provides innovative pathways for advancing Pt-alloy catalyst systems and novel approaches for the improvement of MOR catalysts.