Synthesis of hexagonal boron arsenide nanosheets for low-power consumption flexible memristors

Boron arsenide has recently attracted significant attention for its thermal and electronic properties. However, its lengthy growth process and bulk structure limit its application in advanced semiconductor systems. In this study, we introduce a method for synthesizing ultrathin crystalline hexagonal boron arsenide (h-BAs) nanosheets in large quantities via an in-situ chemical reaction of sodium borohydride with elemental arsenic in a low-pressure hydrogen atmosphere. We successfully fabricated h-BAs-based memory devices with ON/OFF current ratios up to 10<sup>9</sup>, low energy consumption of less than 4.65 pJ, and commendable stability. Furthermore, we have developed flexible h-BAs-based memristors with good stability and robustness. This research not only provides a promising avenue for synthesizing h-BAs nanosheets, but also underscores their potential in the development of next-generation electronic devices.

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Publication Details

Journal
Nature Communications
Published
2025-05-22
DOI
https://doi.org/10.1038/s41467-025-60038-3
Citations
7
Primary Topic
Advanced Memory and Neural Computing
Type
article
Field-Weighted Citation Impact
5.11

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Synthesis of hexagonal boron arsenide nanosheets for low-power consumption flexible memristors

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Synthesis of hexagonal boron arsenide nanosheets for low-power consumption flexible memristors

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article en
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Abstract

Boron arsenide has recently attracted significant attention for its thermal and electronic properties. However, its lengthy growth process and bulk structure limit its application in advanced semiconductor systems. In this study, we introduce a method for synthesizing ultrathin crystalline hexagonal boron arsenide (h-BAs) nanosheets in large quantities via an in-situ chemical reaction of sodium borohydride with elemental arsenic in a low-pressure hydrogen atmosphere. We successfully fabricated h-BAs-based memory devices with ON/OFF current ratios up to 10<sup>9</sup>, low energy consumption of less than 4.65 pJ, and commendable stability. Furthermore, we have developed flexible h-BAs-based memristors with good stability and robustness. This research not only provides a promising avenue for synthesizing h-BAs nanosheets, but also underscores their potential in the development of next-generation electronic devices.

Nature CommunicationsVol. 16(1)
Kyushu University (JP), City University of Hong Kong (HK), Shenzhen University (CN), Kyushu University Hospital (JP), City University of Hong Kong, Shenzhen Research Institute (CN)
University Grants Committee
Affordable and clean energy
Openalex Percentile: Top 5%
Advanced Memory and Neural Computing
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