Chelation-controlled stereospecific ring-opening arylation of α-aminoaryl-tethered alkylidenecyclopropanes: stereoselective synthesis of polysubstituted conjugated dienes

A palladium-catalyzed stereospecific ring-opening arylation of α-aminoaryl-tethered alkylidenecyclopropanes for the stereoselective synthesis of 1,1,2-trisubstituted conjugated dienes has been developed.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo00496a
Primary Topic
Cyclopropane Reaction Mechanisms
Type
article
Field-Weighted Citation Impact
0.00

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article

Chelation-controlled stereospecific ring-opening arylation of α-aminoaryl-tethered alkylidenecyclopropanes: stereoselective synthesis of polysubstituted conjugated dienes

Ying Tang, Yong-Yu He, W. LUO, Ai‐Jun Ma et al.
Organic Chemistry Frontiers
Cyclopropane Reaction Mechanisms
article

Chelation-controlled stereospecific ring-opening arylation of α-aminoaryl-tethered alkylidenecyclopropanes: stereoselective synthesis of polysubstituted conjugated dienes

Ying Tang, Yong-Yu He, W. LUO, Ai‐Jun Ma, Jin‐Bao Peng, Miao-Miao Ji
article en

Abstract

A palladium-catalyzed stereospecific ring-opening arylation of α-aminoaryl-tethered alkylidenecyclopropanes for the stereoselective synthesis of 1,1,2-trisubstituted conjugated dienes has been developed.

Organic Chemistry FrontiersVol. 12(19)
Wuyi University (CN)
Wuyi University, Department of Education of Guangdong Province
Openalex Percentile: Top 91%
Cyclopropane Reaction Mechanisms
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