Uncommon quadruple stacking topology in a honeycomb-sheet MOF compatible with through-space conduction
Quadruple stacking topology with an unusual threefold stacking periodicity in four honeycomb sheets was realized in a flexible wavy honeycomb-sheet MOF (PMC-20). The infinite π-stacked arrays, formed exclusively at the π-conjugated core of the linker site, contribute to the highest electrical conductivity among the reported naphthalenediimide (NDI)-based crystals.
Authors
- Liyuan Qu
- Tappei Tanabe
- Kensuke Ueno (ORCID: https://orcid.org/0000-0002-7754-6277)
- Yuh Hijikata (ORCID: https://orcid.org/0000-0003-4883-5085)
- Ryotaro Matsuda (ORCID: https://orcid.org/0000-0002-7665-6212)
- Hiroaki Iguchi (ORCID: https://orcid.org/0000-0001-5368-3157)
- Masahiro Yamashita (ORCID: https://orcid.org/0000-0001-5739-7326)
- Ryota Sakamoto (ORCID: https://orcid.org/0000-0002-8702-1378)
- Shinya Takaishi (ORCID: https://orcid.org/0000-0002-6739-8119)
Institutions
- Tongji University (CN)
- Tohoku University (JP)
- Nagoya University (JP)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc00084j
- Citations
- 5
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 2.69
Funders
- Japan Science and Technology Corporation
- Iketani Science and Technology Foundation
- Murata Science Foundation
- TOBE MAKI Scholarship Foundation
- Japan Society for the Promotion of Science