Symmetrical and unsymmetrical thiophosphoryl-thiocarbamate pincer ligands: cyclopalladation in solution and under solvent-free conditions
The modern concept of green chemistry calls for the development of more environmentally benign synthetic protocols and a reduction in the use of auxiliary substances, including solvents. In this work the effect of a thiophosphoryl pendant arm on the cyclopalladation features of both symmetrical and unsymmetrical thiocarbamate pincer ligands was explored. The ligands were 1,3-bis(carbamoyloxy)-5-(diphenylthiophosphoryl)- or 1-carbamoyloxy-3-(diphenylthiophosphoryl)benzenes, the palladium source was (PhCN)<sub>2</sub>PdCl<sub>2</sub>.
Authors
- Diana V. Aleksanyan (ORCID: https://orcid.org/0000-0002-7083-2537)
- Kozlov Va (ORCID: https://orcid.org/0000-0002-1756-1782)
- Aleksander M. Shakhov
- Yulia Vladimirovna Nelyubina (ORCID: https://orcid.org/0000-0002-9121-0040)
- Zinaida S. Klemenkova
- С. Е. Соловьева
Institutions
- Semenov Institute of Chemical Physics (RU)
- A. N. Nesmeyanov Institute of Organoelement Compounds (RU)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
- Institute of Problems of Chemical Physics (RU)
Publication Details
- Journal
- Mendeleev Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.71267/mencom.7705
- Citations
- 1
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.94
Funders
- Ministry of Education and Science of the Russian Federation
- Russian Science Foundation