Electrochemical behavior of bridged 1,2,4-dioxazolidine derivative in acetonitrile medium on the smooth gold
Bridged bicyclic peroxide with 1,2,4-dioxazolidine core, namely, ethyl 2-(4-chlorobenzyl)-1,5-dimethyl-6,7-dioxa-8- azabicyclo[3.2.1]octane-2-carboxylate, was studied by cyclic voltammetry in acetonitrile medium on a smooth gold electrode. During the cathode process, two electrons are transferred, with the first electron transfer being reversible; a mechanism of cathode reduction of the substrate involves acetonitrile as the source of protons. The anodic oxidation involves the formation of colloidal gold particles due to corrosion of the gold electrode.
Authors
- Yulia Yu. Belyakova (ORCID: https://orcid.org/0009-0004-0870-6582)
- А. М. Скундин (ORCID: https://orcid.org/0000-0001-7627-5703)
- M. V. Polyakov (ORCID: https://orcid.org/0009-0007-2861-9074)
- Ivan A. Yaremenko (ORCID: https://orcid.org/0000-0003-1068-9051)
- Peter S. Radulov (ORCID: https://orcid.org/0000-0003-2653-0395)
- M. D. Vedenyapina
Institutions
- Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (RU)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
Publication Details
- Journal
- Mendeleev Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.71267/mencom.7714
- Citations
- 1
- Primary Topic
- Conducting polymers and applications
- Type
- article
- Field-Weighted Citation Impact
- 0.61
Funders
- Ministry of Education and Science of the Russian Federation