Thiacalixarene-supported M<sub>20</sub>V<sub>8</sub> (M = Fe, Co, Ni) square pyramid nanocages for visible light photothermal catalysis
We rationally designed and synthesized a series of square pyramid nanocages (M<sub>20</sub>V<sub>8</sub>, M = Fe, Co, Ni) based on M<sub>4</sub>-TC4A (H<sub>4</sub>TC4A = <i>p-tert</i>-butylthiacalix[4]arene) polynuclear secondary building units (PSBUs) and vanadate anion units in {5+8} condensation modes. Among them, the Fe<sub>20</sub>V<sub>8</sub> cage exhibited significant photothermal conversion efficiency (up to 80%) and photothermal catalytic performance for the oxidation desulfurization of thioether.
Authors
- Yuhan Zou
- Hongrui Tian (ORCID: https://orcid.org/0000-0003-2550-219X)
- D. Mao (ORCID: https://orcid.org/0000-0002-9976-4013)
- Yanfeng Bi (ORCID: https://orcid.org/0000-0003-0588-0679)
- Xinxin Hang (ORCID: https://orcid.org/0000-0002-0567-2653)
- Qiqi Li (ORCID: https://orcid.org/0000-0002-2544-7453)
Institutions
- Liaoning Shihua University (CN)
- Yangzhou University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02007g
- Citations
- 4
- Primary Topic
- Porphyrin and Phthalocyanine Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 2.07