Synthesis of the tricyclic skeleton of aberrarone
A synthesis of the 6-5-5 tricyclic skeleton of the diterpenoid aberrarone is reported. The synthesis strategically features an intermolecular Diels-Alder reaction to construct the <i>cis</i>-hydrindane moiety and a cross-coupling-isomerization-intramolecular Alder-ene cyclization cascade to efficiently assemble the 6-5-5 tricyclic skeleton of aberrarone.
Authors
- Xiaoqing Song (ORCID: https://orcid.org/0000-0002-6243-722X)
- Hong‐Dong Hao (ORCID: https://orcid.org/0000-0002-9236-3727)
- Xiaolan Xie
- Guoqing Sui
- Huihui� Guo (ORCID: https://orcid.org/0009-0002-4772-7381)
- Wenming Zhou (ORCID: https://orcid.org/0000-0001-5201-8833)
- Li Ren
Institutions
- Weifang University (CN)
- Northwest A&F University (CN)
Publication Details
- Journal
- Organic & Biomolecular Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ob00644a
- Citations
- 2
- Primary Topic
- Synthetic Organic Chemistry Methods
- Type
- article
- Field-Weighted Citation Impact
- 1.87
Funders
- National Natural Science Foundation of China