Unexpected cyclization of β-(hydroxymethyl)phosphole into 1-phospha-1,6a-dihydrophosphapentalene: a fused 1,3-butadiene-based luminophore
During the planned synthesis of carbon-bridged fused phospholes, an unexpected intramolecular cyclization of β-(hydroxymethyl)phosphole yielded 1-phospha-1,6a-dihydropentalene, besides the expected cyclized product. The solid-state emission of 1-phospha-1,6a-dihydropentalene indicates its potential as a 1,3-butadiene-based solid-state luminophore.
Authors
- Hiroshi Imahori (ORCID: https://orcid.org/0000-0003-3506-5608)
- Tomohiro Higashino (ORCID: https://orcid.org/0000-0002-9531-8569)
- Riku Minobe
- Tomoya Machino
Institutions
- Kyoto University (JP)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02428e
- Citations
- 2
- Primary Topic
- Synthesis and characterization of novel inorganic/organometallic compounds
- Type
- article
- Field-Weighted Citation Impact
- 1.07
Funders
- Japan Society for the Promotion of Science