Heteropolynuclear PdAg<sub>4</sub> complexes with self-assembled <i>trans</i>-chelating {(Ar<sub>2</sub>pz)<sub>3</sub>Ag<sub>2</sub>} units
Herein, we report novel square-planar Pd(II) complexes bearing two Ag<sub>2</sub>(Ar<sub>2</sub>pz)<sub>3</sub> units as self-assembled <i>trans</i>-chelating ligands. This structural motif is unique to Pd(II) ions and cannot be obtained from a Pt(II) metal source owing to the stronger dative bonding nature of the Pt(II) ion compared to that of the Pd(II) ion.
Authors
- Katsuhiro Kinoshita
- Shingo Nagano (ORCID: https://orcid.org/0000-0002-9292-8759)
- Shinnosuke Horiuchi (ORCID: https://orcid.org/0000-0002-5692-6377)
- Eri Sakuda (ORCID: https://orcid.org/0000-0001-9882-7628)
- Keisuke Umakoshi (ORCID: https://orcid.org/0000-0002-2027-6333)
- Kenichiro Omoto (ORCID: https://orcid.org/0000-0002-4134-3005)
- Yasuhiro Arikawa (ORCID: https://orcid.org/0000-0001-6727-2340)
- Yoshihide Nakao
- Yiming Yang
Institutions
- Kyushu Sangyo University (JP)
- Nagasaki University (JP)
- The University of Tokyo (JP)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt01078k
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00