Unconventional catalytic kinetics of dual field regulated pyrochlore-type high-entropy ceramics towards the Li<sub>2</sub>S<sub>4</sub> intermediate
Reducing the electronegativity and crystal field splitting energy can adjust the Zr–O covalency and electronic structure. This, in turn, weakens the adsorption ability of pyrochlore high-entropy oxides towards Li 2 S 4 and enhances sulfur redox catalysis.
Authors
- Prashanth Wilfred Menezes (ORCID: https://orcid.org/0000-0002-0665-7690)
- Ziliang Chen (ORCID: https://orcid.org/0000-0001-5307-7309)
- Handing Liu (ORCID: https://orcid.org/0009-0004-9111-2610)
- G.J. Zhang (ORCID: https://orcid.org/0000-0002-8509-3351)
- Lin Zhou (ORCID: https://orcid.org/0000-0003-4867-1471)
- Xinrui Zhang (ORCID: https://orcid.org/0009-0000-4062-3040)
- Ruirui Wang (ORCID: https://orcid.org/0000-0003-1445-2537)
- Jixuan Liu (ORCID: https://orcid.org/0000-0001-9703-9224)
- Yixi Yao
Institutions
- Donghua University (CN)
- Helmholtz-Zentrum Berlin für Materialien und Energie (DE)
- Suzhou University of Science and Technology (CN)
- Soochow University (CN)
- HKUST Shenzhen Research Institute (CN)
- Peking University Shenzhen Hospital (CN)
- Technische Universität Berlin (DE)
- University of Hong Kong (HK)
Publication Details
- Journal
- Energy & Environmental Science
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ee01215e
- Citations
- 4
- Primary Topic
- Advanced materials and composites
- Type
- article
- Field-Weighted Citation Impact
- 2.85
Funders
- International Education Research Foundation
- National Natural Science Foundation of China
- Bundesministerium für Bildung und Forschung