Copper‐Photoredox‐Catalyzed C(sp <sup>3</sup> )–C(sp <sup>3</sup> ) Reductive Cross‐Coupling of Alkyl Bromides with BCP‐Thianthrenium Reagents
Herein, we report a reductive cross-coupling reaction of bicyclo[1.1.1]pentyl (BCP)-thianthrenium reagents and alkyl bromides. The reaction is catalyzed by a copper/photoredox catalyst system. The approach is the first example of a cross-coupling between BCP-based reagents with alkyl electrophiles.
Authors
- Tobias Ritter (ORCID: https://orcid.org/0000-0002-6957-450X)
- Saikat Pandit
Institutions
- Max-Planck-Institut für Kohlenforschung (DE)
- RWTH Aachen University (DE)
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2025-05-20
- DOI
- https://doi.org/10.1002/anie.202506785
- Citations
- 9
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 8.42