Thermochemical characteristics of Ce95Al5 material and perforation behavior of its liner on steel targets

Cerium-aluminum (CeAl) alloy is promising reactive structural materials (RSMs) with significant potential for liner applications. To investigate the thermochemical characteristics of CeAl alloy and the perforation behavior of its liner impacting steel targets, a CeAl alloy liner with 5 wt% Al content was fabricated, with a cerium (Ce) liner and a copper (Cu) liner used as control. The microstructure and elemental distribution of the CeAl alloy were analyzed using SEM, EDS, and XRD. The thermochemical reaction mechanism of the CeAl alloy was examined through TG-DSC. Penetration experiments were conducted to explore the combined effects of invasion and implosion of CeAl alloy liner against steel target. The results indicate that the addition of Al leads to the formation of Ce 3 Al intermetallic compounds in the alloy and reduces the apparent activation energy of the Ce-based alloy by around 53.17%, thereby facilitating energy release. The presence of 5 wt% Al increases the calorific value by approximately 24.5%, and this change allows the oxidation process to be divided into three distinct stages. Compared to an inert copper liner, the average penetration diameter of the CeAl5 reactive alloy liner increases by around 42.78%. Furthermore, when compared to the Ce liner, the penetration depth of the CeAl5 reactive alloy liner increases by approximately 82.64%.

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Publication Details

Journal
Defence Technology
Published
2025-05-20
DOI
https://doi.org/10.1016/j.dt.2025.05.017
Primary Topic
Intermetallics and Advanced Alloy Properties
Type
article
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article

Thermochemical characteristics of Ce95Al5 material and perforation behavior of its liner on steel targets

Peiying Li, Chunlan Jiang, Xiongbo Feng, Liang Mao et al.
4 links
Defence Technology
Intermetallics and Advanced Alloy Properties
article

Thermochemical characteristics of Ce95Al5 material and perforation behavior of its liner on steel targets

Peiying Li, Chunlan Jiang, Xiongbo Feng, Liang Mao, Guitao Liu, Baolin Wang, Yitong Liu, Zirui Jiang
article en

Abstract

Cerium-aluminum (CeAl) alloy is promising reactive structural materials (RSMs) with significant potential for liner applications. To investigate the thermochemical characteristics of CeAl alloy and the perforation behavior of its liner impacting steel targets, a CeAl alloy liner with 5 wt% Al content was fabricated, with a cerium (Ce) liner and a copper (Cu) liner used as control. The microstructure and elemental distribution of the CeAl alloy were analyzed using SEM, EDS, and XRD. The thermochemical reaction mechanism of the CeAl alloy was examined through TG-DSC. Penetration experiments were conducted to explore the combined effects of invasion and implosion of CeAl alloy liner against steel target. The results indicate that the addition of Al leads to the formation of Ce 3 Al intermetallic compounds in the alloy and reduces the apparent activation energy of the Ce-based alloy by around 53.17%, thereby facilitating energy release. The presence of 5 wt% Al increases the calorific value by approximately 24.5%, and this change allows the oxidation process to be divided into three distinct stages. Compared to an inert copper liner, the average penetration diameter of the CeAl5 reactive alloy liner increases by around 42.78%. Furthermore, when compared to the Ce liner, the penetration depth of the CeAl5 reactive alloy liner increases by approximately 82.64%.

Defence TechnologyVol. 54
Beijing Institute of Technology (CN), Shanxi Provincial Institute of Chemical Industry (China) (CN)
Openalex Percentile: Top 89%
Intermetallics and Advanced Alloy Properties
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Thermochemical characteristics of Ce95Al5 material and perforation behavior of its liner on steel targets — Peiying Li, Chunlan Jiang, et al. · Defence Technology (2025) | TGRS Research Map | TGRS