Short-bite PSP-type ligands: coordination chemistry and ligand rearrangement reactions
Sulphur-containing short-bite diphosphine ligands are widely overlooked despite their analogy to well-explored PCP-based ligands. This work investigates the impact of the monoatomic sulphur-based ligand backbone in nickel complexes [NiHal<sub>2</sub>(PSP)], PSP = Ph<sub>2</sub>PSPPh<sub>2</sub>, Hal = Br (1), I (2) as counterparts of related [NiHal<sub>2</sub>(PCP)] complexes. The highly flexible PSP ligand backbone has shown a postive effect in Kumada-Tamao-Corriu coupling reactions of sterically demanding substrates.
Authors
- Toni Grell (ORCID: https://orcid.org/0000-0001-9162-6487)
- Franziska Flecken (ORCID: https://orcid.org/0000-0003-4418-7455)
- Schirin Hanf (ORCID: https://orcid.org/0000-0003-2624-7872)
Institutions
- Karlsruhe Institute of Technology (DE)
- University of Milan (IT)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc01739d
- Citations
- 1
- Primary Topic
- Metal complexes synthesis and properties
- Type
- article
- Field-Weighted Citation Impact
- 1.05
Funders
- Stiftung der Deutschen Wirtschaft