Copper‐Photoredox‐Catalyzed C(sp <sup>3</sup> )–C(sp <sup>3</sup> ) Reductive Cross‐Coupling of Alkyl Bromides with BCP‐Thianthrenium Reagents

Abstract Herein, we report a reductive cross‐coupling reaction of bicyclo[1.1.1]pentyl (BCP)‐thianthrenium reagents and alkyl bromides. The reaction is catalyzed by a copper/photoredox catalyst system. The approach is the first example of a cross‐coupling between BCP‐based reagents with alkyl electrophiles.

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Publication Details

Journal
Angewandte Chemie
Published
2025-05-20
DOI
https://doi.org/10.1002/ange.202506785
Citations
1
Primary Topic
Catalytic C–H Functionalization Methods
Type
article
Field-Weighted Citation Impact
0.94
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article

Copper‐Photoredox‐Catalyzed C(sp 3 )–C(sp 3 ) Reductive Cross‐Coupling of Alkyl Bromides with BCP‐Thianthrenium Reagents

Tobias Ritter, Saikat Pandit
1 citations
Angewandte Chemie
Catalytic C–H Functionalization Methods
0.94
article

Copper‐Photoredox‐Catalyzed C(sp 3 )–C(sp 3 ) Reductive Cross‐Coupling of Alkyl Bromides with BCP‐Thianthrenium Reagents

Tobias Ritter, Saikat Pandit
article en
1 citations

Abstract

Abstract Herein, we report a reductive cross‐coupling reaction of bicyclo[1.1.1]pentyl (BCP)‐thianthrenium reagents and alkyl bromides. The reaction is catalyzed by a copper/photoredox catalyst system. The approach is the first example of a cross‐coupling between BCP‐based reagents with alkyl electrophiles.

Angewandte ChemieVol. 137(30)
Max-Planck-Institut für Kohlenforschung (DE), RWTH Aachen University (DE)
Openalex Percentile: Top 26%
Catalytic C–H Functionalization Methods
0.94
DOIOpen Access PDFOpenAlex
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Copper‐Photoredox‐Catalyzed C(sp <sup>3</sup> )–C(sp <sup>3</sup> ) Reductive Cross‐Coupling of Alkyl Bromides with BCP‐Thianthrenium Reagents — Tobias Ritter, Saikat Pandit · Angewandte Chemie (2025) | TGRS Research Map | TGRS