Commercial organic Lewis-pair catalysts for efficient ring-opening polymerization of 1,2-butylene oxide

The metal-free Lewis pair catalytic system (Et 3 B and TBPBr) enables to deliver high molecular weight PBO with a narrow polydispersity index and allows precise synthesis of low molecular weight PBO polyols using diols as initiators.

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Publication Details

Journal
Polymer Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5py00238a
Primary Topic
Carbon dioxide utilization in catalysis
Type
article
Field-Weighted Citation Impact
0.00

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article

Commercial organic Lewis-pair catalysts for efficient ring-opening polymerization of 1,2-butylene oxide

Peng He, Xianqiang Zeng, Chen Liu, Yan Cao et al.
Polymer Chemistry
Carbon dioxide utilization in catalysis
article

Commercial organic Lewis-pair catalysts for efficient ring-opening polymerization of 1,2-butylene oxide

Peng He, Xianqiang Zeng, Chen Liu, Yan Cao, Liguo Wang, Huiquan Li, Zheng Zheng, Xue Wang
article en

Abstract

The metal-free Lewis pair catalytic system (Et 3 B and TBPBr) enables to deliver high molecular weight PBO with a narrow polydispersity index and allows precise synthesis of low molecular weight PBO polyols using diols as initiators.

Polymer ChemistryVol. 16(23)
Institute of Process Engineering (CN), University of Chinese Academy of Sciences (CN)
National Key Research and Development Program of China
Openalex Percentile: Top 92%
Carbon dioxide utilization in catalysis
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