Highly Stretchable, Low Hysteresis, and Transparent Ionogels as Conductors for Dielectric Elastomer Actuators

As conductive materials, ionogels have attracted significant attention for their potential applications in flexible wearable electronics. However, preparing an ionogel with mechanical properties akin to human skin while also achieving transparency, adhesion, and low hysteresis through simple processes remains challenging. Here, we introduce a multifunctional ionogel synthesized via a one-step photopolymerization method. By leveraging the good compatibility between the ionic liquid and the polymer network, as well as the hydrogen bonding and chemical crosslinking within the gel network, we achieved an ionogel with high transparency (>98%), stretchability (fracture strain of 19), low hysteresis (<5.83%), strong adhesion, robust mechanical stability, excellent electrical properties, a wide operating temperature range, and a tunable modulus (1-103 kPa) that matches human skin. When used as a conductor in soft actuators, the ionogel enabled a large area strain of 36% and a fast electromechanical conversion time of less than 1 s. The actuator demonstrated good actuation performance with voltage and frequency dependence, electrochemical stability, and outstanding durability over millions of cycles. This study provides a simple and effective method to produce multifunctional ionogels with tailored mechanical properties that match those of human skin, paving the way for their application in flexible wearable electronics.