Branched Polyethylene Synthesized by Salicylaldiminato Nickel Complexes with an Ethereal Donor Group

Many late-transition-metal catalysts have been developed for the synthesis of branched polyethylene. However, the methods for the synthesis of low molecular weight and highly branched polyethylene are limited. Here we report the facile synthesis of a series of salicylaldiminato nickel complexes with an ethereal donor hemilabile group and their application in ethylene polymerization to produce low molecular weight highly branched polyethylene effectively.

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Publication Details

Journal
Organometallics
Published
2025-05-19
DOI
https://doi.org/10.1021/acs.organomet.5c00018
Citations
1
Primary Topic
Organometallic Complex Synthesis and Catalysis
Type
article
Field-Weighted Citation Impact
0.94

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article

Branched Polyethylene Synthesized by Salicylaldiminato Nickel Complexes with an Ethereal Donor Group

Dongcai Shen, Yi Wu, Wenjie Tao, Renrong Liu et al.
1 citations
Organometallics
Organometallic Complex Synthesis and Catalysis
0.94
article

Branched Polyethylene Synthesized by Salicylaldiminato Nickel Complexes with an Ethereal Donor Group

Dongcai Shen, Yi Wu, Wenjie Tao, Renrong Liu, Chenggong Sang, Inzamam Abbasi
article en
1 citations

Abstract

Many late-transition-metal catalysts have been developed for the synthesis of branched polyethylene. However, the methods for the synthesis of low molecular weight and highly branched polyethylene are limited. Here we report the facile synthesis of a series of salicylaldiminato nickel complexes with an ethereal donor hemilabile group and their application in ethylene polymerization to produce low molecular weight highly branched polyethylene effectively.

OrganometallicsVol. 44(11)
Qingdao University (CN), Chinese Academy of Sciences (CN), Qingdao Institute of Bioenergy and Bioprocess Technology (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 26%
Organometallic Complex Synthesis and Catalysis
0.94
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