Isoreticular Synthesis of Mesoporous Metal‐Organic Polyhedra with Permanent Porosity to Gas and Water

Abstract Synthesis of mesoporous metal‐organic cages or polyhedra (MOCs or MOPs) that retain their porous functionality in the solid‐state remains challenging, given their tendency to collapse upon desolvation. Herein, we report the use of the isoreticular expansion approach to synthesize two permanently porous Rh(II)‐based octahedral MOPs within the mesoporous regime. Our mesoporous MOPs, featuring internal cavities of up to 12.5 nm 3 , withstand the activation process, enabling their use as solid‐state adsorbents for gases and water. In particular, the largest mesoporous MOP, named BCN‐17, captures up to 0.47 g water ·g MOP −1 and exhibits an S‐shaped water‐sorption isotherm with a hysteresis loop, characteristic of mesoporous materials.

Authors

Institutions

Publication Details

Journal
Angewandte Chemie
Published
2025-05-19
DOI
https://doi.org/10.1002/ange.202505682
Primary Topic
Metal-Organic Frameworks: Synthesis and Applications
Type
article
Field-Weighted Citation Impact
0.00

Funders

Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Isoreticular Synthesis of Mesoporous Metal‐Organic Polyhedra with Permanent Porosity to Gas and Water

Inhar Imaz, Judith Juanhuix, Laura Hernández‐López, José A. Suárez del Pino et al.
Angewandte Chemie
Metal-Organic Frameworks: Synthesis and Applications
article

Isoreticular Synthesis of Mesoporous Metal‐Organic Polyhedra with Permanent Porosity to Gas and Water

Inhar Imaz, Judith Juanhuix, Laura Hernández‐López, José A. Suárez del Pino, Yunhui Yang, Cornelia von Baeckmann, Roberto Sánchez‐Naya, Arnau Carné‐Sánchez, Pilar Fernández‐Seriñán, Maryory Astrid Gómez Botero, Daniel Maspoch, Alba Cortés‐Martínez, Caterina Caules
article en

Abstract

Abstract Synthesis of mesoporous metal‐organic cages or polyhedra (MOCs or MOPs) that retain their porous functionality in the solid‐state remains challenging, given their tendency to collapse upon desolvation. Herein, we report the use of the isoreticular expansion approach to synthesize two permanently porous Rh(II)‐based octahedral MOPs within the mesoporous regime. Our mesoporous MOPs, featuring internal cavities of up to 12.5 nm 3 , withstand the activation process, enabling their use as solid‐state adsorbents for gases and water. In particular, the largest mesoporous MOP, named BCN‐17, captures up to 0.47 g water ·g MOP −1 and exhibits an S‐shaped water‐sorption isotherm with a hysteresis loop, characteristic of mesoporous materials.

Angewandte ChemieVol. 137(30)
Institució Catalana de Recerca i Estudis Avançats (ES), Universitat Autònoma de Barcelona (ES), ALBA Synchrotron (Spain) (ES), Institut Català de Nanociència i Nanotecnologia (ES)
Ministerio de Ciencia e Innovación, H2020 European Research Council
Openalex Percentile: Top 91%
Metal-Organic Frameworks: Synthesis and Applications
DOISourceOpenAlex
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.

Isoreticular Synthesis of Mesoporous Metal‐Organic Polyhedra with Permanent Porosity to Gas and Water — Inhar Imaz, Judith Juanhuix, et al. · Angewandte Chemie (2025) | TGRS Research Map | TGRS