Theory of quasistatically screened electron-polar optical phonon scattering

The scattering of electrons with polar optical phonons (POP) is an important mechanism that limits electronic transport and determines electron mobility in polar materials. This is typically a stronger mechanism compared to nonpolar acoustic and optical phonon scattering and of similar strength to the Coulomb ionized impurity scattering. At high densities, on the other hand, the cloud of charge carriers screens the dipoles that are responsible for POP scattering and weakens the electron-POP scattering strength. However, in contrast to ionized impurity scattering, for which the well-known Brooks-Herring equation provides the scattering rates with the effect of screening included, for scattering with POP there is no such closed-form mathematical expression. In this work, we derive such an expression based on Fermi's golden rule, which would prove particularly useful in understanding electronic transport in complex crystal and complex band structure materials, in which electron-POP scattering could dominate electronic transport.

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Publication Details

Journal
Physical review. B./Physical review. B
Published
2025-05-19
DOI
https://doi.org/10.1103/physrevb.111.195211
Citations
6
Primary Topic
Machine Learning in Materials Science
Type
article
Field-Weighted Citation Impact
3.11

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article

Theory of quasistatically screened electron-polar optical phonon scattering

Rajeev Dutt, Neophytos Neophytou, Y. Go
6 citations
Physical review. B./Physical review. B
Machine Learning in Materials Science
3.11
article

Theory of quasistatically screened electron-polar optical phonon scattering

Rajeev Dutt, Neophytos Neophytou, Y. Go
article en
6 citations

Abstract

The scattering of electrons with polar optical phonons (POP) is an important mechanism that limits electronic transport and determines electron mobility in polar materials. This is typically a stronger mechanism compared to nonpolar acoustic and optical phonon scattering and of similar strength to the Coulomb ionized impurity scattering. At high densities, on the other hand, the cloud of charge carriers screens the dipoles that are responsible for POP scattering and weakens the electron-POP scattering strength. However, in contrast to ionized impurity scattering, for which the well-known Brooks-Herring equation provides the scattering rates with the effect of screening included, for scattering with POP there is no such closed-form mathematical expression. In this work, we derive such an expression based on Fermi's golden rule, which would prove particularly useful in understanding electronic transport in complex crystal and complex band structure materials, in which electron-POP scattering could dominate electronic transport.

Physical review. B./Physical review. BVol. 111(19)
University of Warwick (GB)
Engineering and Physical Sciences Research Council
Openalex Percentile: Top 8%
Machine Learning in Materials Science
3.11
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