Phenylene Cage Synthesized by Metal‐Mediated Assembly of Phenylene Macrocycle and Its Piezofluorochromic Behavior
Abstract A phenylene macrocycle containing two meta‐phenylene units positioned opposite each other was used as a building block to construct phenylene cages via platinum‐mediated C─C coupling. A phenylene cage (PC[10]3), consisting of three phenylene macrocycle units, was successfully synthesized and thoroughly characterized using nuclear magnetic resonance (NMR) spectroscopy and single‐crystal X‐ray diffraction. PC[10]3 exhibited significant backbone strain and displayed bright blue emission with a quantum yield of 96%. Additionally, PC[10]3 exhibited a broader and more pronounced piezofluorochromic response compared to its macrocyclic unit, undergoing a distinct photoluminescence shift from blue to yellow–green under pressure. This work opens new avenues for designing and synthesizing hydrocarbon nanocages.
Authors
- Jiang‐Feng Xing (ORCID: https://orcid.org/0009-0000-3925-9130)
- Guanjun Xiao (ORCID: https://orcid.org/0000-0002-7013-1378)
- Xuan‐Wen Chen (ORCID: https://orcid.org/0000-0003-2277-4093)
- Bo Zou (ORCID: https://orcid.org/0000-0002-3215-1255)
- Yuan‐Zhi Tan (ORCID: https://orcid.org/0000-0002-1268-2761)
- Xihan Yu (ORCID: https://orcid.org/0000-0001-9339-6347)
- Bing‐Hui Zheng
- Qingsong Deng (ORCID: https://orcid.org/0009-0003-9234-2437)
Institutions
- Xiamen University (CN)
- Jilin University (CN)
- Collaborative Innovation Center of Chemistry for Energy Materials (CN)
Publication Details
- Journal
- Angewandte Chemie
- Published
- 2025-05-19
- DOI
- https://doi.org/10.1002/ange.202506376
- Citations
- 1
- Primary Topic
- Synthesis and Properties of Aromatic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.94
Funders
- National Natural Science Foundation of China