Optimizing the electron donation and back-donation effect through the combination of d-block transition metal and s-block calcium atoms for efficient nitrogen fixation
The synergistic effect of transition metals and calcium dual-atomic sites optimizes the electron “donation–back-donation” interaction between the metal centers and N 2 , thereby promoting the N 2 electrochemical reduction to NH 3 .
Authors
- Xijun Wang (ORCID: https://orcid.org/0000-0001-9155-7653)
- Ling Zhu (ORCID: https://orcid.org/0000-0002-1815-5831)
- Shaobin Tang (ORCID: https://orcid.org/0000-0002-2969-8698)
- Lingli Liu (ORCID: https://orcid.org/0000-0003-3794-7946)
- Guanping Wei
- Zongchang Mao
- Tiantian Hao
Institutions
- Northwestern University (US)
- Gannan Normal University (CN)
Publication Details
- Journal
- Journal of Materials Chemistry A
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ta02606g
- Citations
- 4
- Primary Topic
- Ammonia Synthesis and Nitrogen Reduction
- Type
- article
- Field-Weighted Citation Impact
- 1.56
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Jiangxi Province