Adaptive hydrogen-bonding strategy driven 0D manganese-based metal halides with multifunctional fluorescent applications
Herein, we designed organic cations with multiple donor and acceptor sites of hydrogen bonds and reported reversible luminescence modulation in 0D manganese-based metal halides <i>via</i> water-driven <i>in situ</i> structural transformations with the above adaptive hydrogen-bonding cation. The non-fluorescent-to-fluorescent transition at human body temperature highlights their high sensitivity and environmental adaptability as promising candidates for advanced fluorescence-based sensing and anti-counterfeiting applications. Besides, the high photoluminescence quantum yield and great stability of fluorescent (BBD)MnBr<sub>4</sub> provide a way to explore OIHMHs pumped by green light for white LEDs.
Authors
- Long Jiang (ORCID: https://orcid.org/0000-0002-3230-4522)
- Dai‐Bin Kuang (ORCID: https://orcid.org/0000-0001-6773-2319)
- Yong Shen (ORCID: https://orcid.org/0000-0002-8605-4848)
- Zhengliang Wang (ORCID: https://orcid.org/0000-0002-5908-4427)
- Yuting Ruan
- Q. H. Qin
- Jiamin Liu (ORCID: https://orcid.org/0000-0003-0118-4852)
Institutions
- Sun Yat-sen University (CN)
- State Ethnic Affairs Commission (CN)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt00491h
- Citations
- 1
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.54