Durability Test and Service Life Prediction Methods for Silicone Structural Glazing Sealant

Silicone structural glazing (SSG) sealants are crucial sealing materials in modern building curtain walls, whose performance degradation may lead to functional and safety issues, posing significant challenges to building safety maintenance. This study comprehensively investigated the effects of temperature, humidity, stress, and ultraviolet (UV) irradiance on the durability of SSG sealants through multi-gradient matrix aging tests, revealing the influence patterns of these four aging factors on tensile bond strength (TBS). Based on aging test data and degradation patterns, a novel degradation model for TBS aging was established by incorporating all four aging factors as variables, enabling the model to reflect their combined effects on TBS degradation. The unknown parameters in the model were calculated using the Markov chain Monte Carlo (MCMC) algorithm and validated against experimental data. A recursive algorithm was developed to predict TBS degradation under actual service conditions based on the degradation model and environmental records, with verification through outdoor aging tests. This study established a service life prediction methodology that combines the degradation model with environmental data through recursive computation and standard-specified strength limits. The results demonstrate that increasing temperature, humidity, stress, and UV irradiation accelerates TBS changes, with influence intensity ranking as UV irradiation > temperature > humidity > stress. Synergistic effects exist among all four factors, where UV irradiation shows the most significant coupling effect by amplifying other factors’ combined impacts, while UV’s primary influence manifests through such synergies rather than independent action. Among temperature, humidity, and stress combined effects, temperature contributes approximately 50%, temperature–humidity interaction about 35%, with temperature-related terms collectively accounting for 90%. The degradation model calculation results show excellent agreement with experimental data (R2 > 0.9, MAE = 0.019 MPa, RMSE = 0.0245 MPa). The characteristic TBS minimum value considering material discreteness and strength assurance rate serves as a reliable criterion for service life evaluation. The proposed prediction method provides essential theoretical and methodological foundations for ensuring long-term safety and maintenance strategies for glass curtain walls.