Cascade C–H functionalization/annulation of 2-aryl-1,3-dicarbonyls with Morita–Baylis–Hillman adducts: access to α-iso-/benzochromenyl acrylates

Pd-catalyzed site-selective C-H functionalization/annulation of 2-aryl-1,3-dicarbonyls with Morita-Baylis-Hillman adducts has been accomplished to produce α-iso-/benzochromenyl acrylates. The cascade C-C and C-O bond formation, product selectivity, substrate scope and functional group tolerance are the important practical features.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc01800e
Primary Topic
Synthesis and Biological Activity
Type
article
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article

Cascade C–H functionalization/annulation of 2-aryl-1,3-dicarbonyls with Morita–Baylis–Hillman adducts: access to α-iso-/benzochromenyl acrylates

Tharmalingam Punniyamurthy, Sharajit Saha, Sounak Roy, Hemanga Bhattacharyya
1 links
Chemical Communications
Synthesis and Biological Activity
article

Cascade C–H functionalization/annulation of 2-aryl-1,3-dicarbonyls with Morita–Baylis–Hillman adducts: access to α-iso-/benzochromenyl acrylates

Tharmalingam Punniyamurthy, Sharajit Saha, Sounak Roy, Hemanga Bhattacharyya
article en

Abstract

Pd-catalyzed site-selective C-H functionalization/annulation of 2-aryl-1,3-dicarbonyls with Morita-Baylis-Hillman adducts has been accomplished to produce α-iso-/benzochromenyl acrylates. The cascade C-C and C-O bond formation, product selectivity, substrate scope and functional group tolerance are the important practical features.

Chemical CommunicationsVol. 61(50)
Indian Institute of Technology Guwahati (IN)
Openalex Percentile: Top 86%
Synthesis and Biological Activity
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