Photochemistry of Methyl Formate Radical Cations in Frozen CFCl3 Matrices
A novel mechanism has been discovered for the phototransformations of methyl formate radical cations (RCs) wherein an RC that is furnished upon thermally induced 1,2-transfer of an hydrogen atom in the methyl group to the bridging oxygen atom undergoes photoinduced H+ transfer to the matrix.
Authors
- Oleg I. Gromov (ORCID: https://orcid.org/0000-0002-4119-8602)
- Mikhail Ya. Melnikov (ORCID: https://orcid.org/0000-0002-9712-8929)
- Ivan D. Sorokin (ORCID: https://orcid.org/0000-0002-3362-531X)
- V. I. Pergushov
- Daria A. Pomogailo
Institutions
- D. Mendeleyev University of Chemical Technology of Russia (RU)
- Lomonosov Moscow State University (RU)
Publication Details
- Journal
- Moscow University Chemistry Bulletin
- Published
- 2025-04-01
- DOI
- https://doi.org/10.3103/s0027131425700026
- Primary Topic
- Atmospheric Ozone and Climate
- Type
- article
- Field-Weighted Citation Impact
- 0.00