How does an antisolvent additive affect all interfaces in aqueous Zn–MnO<sub>2</sub> batteries?
Low levels of acetonitrile (0.5–2 vol%) have the lowest nucleation, growth, and stripping overpotentials at the Zn anode and highest δ-MnO 2 phase reversibility at cathode suggesting a balance between suppressed conversion and retained Zn 2+ mobility.
Authors
- Michael F. Toney (ORCID: https://orcid.org/0000-0002-7513-1166)
- Robert F. Klie (ORCID: https://orcid.org/0000-0003-4773-6667)
- Michael John Counihan (ORCID: https://orcid.org/0000-0003-4535-573X)
- Sanja Tepavcevic (ORCID: https://orcid.org/0000-0003-0151-8832)
- Yingjie Yang (ORCID: https://orcid.org/0000-0002-1898-8171)
- Stefan Ilić (ORCID: https://orcid.org/0000-0002-6305-4001)
- Lacey S. Roberts
- Claire Ely
Institutions
- Argonne National Laboratory (US)
- University of Colorado Boulder (US)
- University of Illinois Chicago (US)
Publication Details
- Journal
- Journal of Materials Chemistry A
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ta00951k
- Citations
- 1
- Primary Topic
- Advanced battery technologies research
- Type
- article
- Field-Weighted Citation Impact
- 0.73
Funders
- National Science Foundation
- U.S. Department of Energy
- Northwestern University
- Office of Science
- University of Colorado Boulder
- Basic Energy Sciences
- Army Research Office
- Argonne National Laboratory