First pyridyl-terminated trigonal-prismatic cobalt( <scp>ii</scp> ) cage-like complex as prospective N-donor highly paramagnetic three-dimensional ligand and probe
The titled compound was prepared by carrying out template condensation of chelating and capping ligand synthons on cobalt(II) ion as a matrix. Its three-dimensional molecule has a trigonal-prismatic geometry favorable for appearance of slow magnetic relaxation. Magnetism measurements, supported by <i>ab initio</i> calculations, revealed its strong uniaxial magnetic anisotropy and zero-field SIM behaviour.
Authors
- A. I. Dmitriev (ORCID: https://orcid.org/0000-0001-9554-4884)
- Alexander S. Belov (ORCID: https://orcid.org/0000-0001-5223-3111)
- Anastasia A. Danshina (ORCID: https://orcid.org/0000-0003-0368-2177)
- Margarita G. Bugaenko (ORCID: https://orcid.org/0009-0009-8573-4401)
- Svetlana A. Belova (ORCID: https://orcid.org/0000-0001-8217-6103)
- Денис В. Корчагин (ORCID: https://orcid.org/0000-0002-0199-1382)
- Mikhail V. Zhidkov (ORCID: https://orcid.org/0000-0001-7513-2057)
- Yan Z. Voloshin (ORCID: https://orcid.org/0000-0003-2823-6560)
Institutions
- A. N. Nesmeyanov Institute of Organoelement Compounds (RU)
- NS Kurnakova Institute of General and Inorganic Chemistry (RU)
- Institute of Problems of Chemical Physics (RU)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt00649j
- Citations
- 1
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.43