Amorphous nickel boride facilitates active site generation for HMF electrooxidation

In this study, we demonstrate an amorphous NiB(O) electrocatalyst for 5-hydroxymethylfurfural oxidation reaction (HMFOR). The distinctive amorphous structure of NiB(O) facilitates rapid reconstruction, accelerating HMFOR kinetics. NiB(O) exhibits a high current density of 300 mA cm<sup>-2</sup> at a low potential of 1.44 V <i>vs.</i> RHE with a yield of 2,5-furanedicarboxylic acid (FDCA) exceeding 92% and a conversion rate approaching 100% during five cycles of HMFOR.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc00799b
Citations
3
Primary Topic
Electrocatalysts for Energy Conversion
Type
article
Field-Weighted Citation Impact
1.09
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article

Amorphous nickel boride facilitates active site generation for HMF electrooxidation

Yi Xiao Wu, Peng Fei Liu, Yi Zhou, Wenhan Jiang et al.
3 citations
Chemical Communications
Electrocatalysts for Energy Conversion
1.09
article

Amorphous nickel boride facilitates active site generation for HMF electrooxidation

Yi Xiao Wu, Peng Fei Liu, Yi Zhou, Wenhan Jiang, Hao Xu, Xin Zhang, Hua Gui Yang, Ji Kai Liu
article en
3 citations

Abstract

In this study, we demonstrate an amorphous NiB(O) electrocatalyst for 5-hydroxymethylfurfural oxidation reaction (HMFOR). The distinctive amorphous structure of NiB(O) facilitates rapid reconstruction, accelerating HMFOR kinetics. NiB(O) exhibits a high current density of 300 mA cm<sup>-2</sup> at a low potential of 1.44 V <i>vs.</i> RHE with a yield of 2,5-furanedicarboxylic acid (FDCA) exceeding 92% and a conversion rate approaching 100% during five cycles of HMFOR.

Chemical CommunicationsVol. 61(49)
East China University of Science and Technology (CN)
Openalex Percentile: Top 24%
Electrocatalysts for Energy Conversion
1.09
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