Preparation and assembly of SiO<sub>2</sub>@TiO<sub>2</sub> photoresponsive colloidal rings

We report the synthesis of SiO<sub>2</sub> colloidal rings coated with TiO<sub>2</sub>, which enable photoresponsive self-assembly into porous ordered structures and hybrid assembly for the capture and release of non-active colloids in a hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) solution. Such assemblies originate from a concentration gradient generated by the TiO<sub>2</sub>-mediated decomposition of H<sub>2</sub>O<sub>2</sub> under ultraviolet (UV) irradiation. The work provides a straightforward strategy to fabricate active colloids with ring-like shapes for the controlled assembly of open crystalline colloidal materials.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc01902h
Primary Topic
TiO2 Photocatalysis and Solar Cells
Type
article
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article

Preparation and assembly of SiO2@TiO2 photoresponsive colloidal rings

Zexin Zhang, Huaguang Wang, Xiaoyu Pan
4 links
Chemical Communications
TiO2 Photocatalysis and Solar Cells
article

Preparation and assembly of SiO2@TiO2 photoresponsive colloidal rings

Zexin Zhang, Huaguang Wang, Xiaoyu Pan
article en

Abstract

We report the synthesis of SiO<sub>2</sub> colloidal rings coated with TiO<sub>2</sub>, which enable photoresponsive self-assembly into porous ordered structures and hybrid assembly for the capture and release of non-active colloids in a hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) solution. Such assemblies originate from a concentration gradient generated by the TiO<sub>2</sub>-mediated decomposition of H<sub>2</sub>O<sub>2</sub> under ultraviolet (UV) irradiation. The work provides a straightforward strategy to fabricate active colloids with ring-like shapes for the controlled assembly of open crystalline colloidal materials.

Chemical CommunicationsVol. 61(48)
Soochow University (CN)
Openalex Percentile: Top 94%
TiO2 Photocatalysis and Solar Cells
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