Absorbance study on the adsorptive removal of Fe(III) ions using activated carbon from coconut shells
This study explores the adsorption kinetics and capacity of Fe(III) ions from aqueous solutions onto activated carbon synthesized from coconut shells. The carbonization process was conducted at 700 °C for 1 h, followed by activation with zinc chloride (ZnCl 2 ) as the activating agent. The resulting activated carbon was characterized using nitrogen adsorption isotherms, X-ray diffraction (XRD), and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS). The absorbance of Fe(III) solutions was quantitatively analyzed using UV–Vis spectroscopy. Activated carbon derived from coconut shells was employed as an adsorbent for Fe(III) Nitrate solutions. The study systematically investigated several parameters influencing the adsorption process, including initial ion concentration, contact time, and varying weights of activated carbon. Characterization results indicated a specific surface area of 490.29 m 2 /g, with a predominately amorphous aromatic carbon structure and a carbon content of approximately 86.41 % by weight. The maximum adsorption capacity for Fe(III) Nitrate was observed to be 60.95 mg/g for a carbon weight of 0.005 g and 50.95 mg/g for a carbon weight of 0.01 g. Notably, the highest removal efficiency reached 83.81 % with an activated carbon weight of 0.5 g. • Activated Carbon Synthesis Coconut shells were carbonized at 700 °C for 1 h and activated using ZnCl 2 as the activating agent. Characterization revealed a surface area of 490.29 m 2 /g, an amorphous aromatic structure, and a carbon content of 86.41 %. • Fe(III) Ion Adsorption kinetics and capacity of Fe(III) ions onto activated carbon were systematically studied. Maximum adsorption capacities were 60.95 mg/g for 0.005 g of carbon and 50.95 mg/g for 0.01 g of carbon. • Optimization of Parameters such as initial Fe(III) concentration, contact time, and adsorbent weight were varied to optimize the adsorption process. Highest removal efficiency of 83.81 % was achieved with 0.5 g of activated carbon. • Characterization Techniques Activated carbon was analyzed using nitrogen adsorption isotherms, XRD, and SEM-EDS. UV–Vis spectroscopy was employed for quantitative analysis of Fe(III) ion concentrations.
Authors
- Otong Nurhilal
- Setianto Setianto (ORCID: https://orcid.org/0000-0002-7049-9236)
- Sahrul Hidayat (ORCID: https://orcid.org/0000-0001-7060-2734)
- Adam Bagaskara
- Aufa Haritsah Sihite
Institutions
- Padjadjaran University (ID)
Publication Details
- Journal
- Current Research in Green and Sustainable Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1016/j.crgsc.2025.100458
- Citations
- 5
- Primary Topic
- Adsorption and biosorption for pollutant removal
- Type
- article
- Field-Weighted Citation Impact
- 4.09
Funders
- Universitas Padjadjaran