Red Light and Supersilane: A Novel Pathway for Hydrofunctionalizations and Giese Reactions
Herein, we describe the photoredox activation of silanes under deep-red irradiation with or without osmium-based photocatalysts to generate silyl radicals. These radicals were further employed for achieving various reactivities previously unexplored in the red-light spectral region, such as hydrosilylation, hydrosulfonylation, and Giese reaction. Overall, the developed deep-red protocols allow for the preparation of a diverse array of high-value molecules.
Authors
- Aakanksha Gurawa (ORCID: https://orcid.org/0000-0002-7408-4388)
- Alexis Prieto (ORCID: https://orcid.org/0000-0002-2922-4652)
- Marc Taillefer (ORCID: https://orcid.org/0000-0003-2991-5418)
Institutions
- École Nationale Supérieure de Chimie de Montpellier (FR)
- Centre National de la Recherche Scientifique (FR)
- Université de Montpellier (FR)
Publication Details
- Journal
- ACS Organic & Inorganic Au
- Published
- 2025-05-10
- DOI
- https://doi.org/10.1021/acsorginorgau.5c00032
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Centre National de la Recherche Scientifique
- Université de Montpellier